STEARIC ACID
|
PRODUCT
IDENTIFICATION
|
CAS
NO.
|
57-11-4 |
|
EINECS NO. |
200-313-4 |
FORMULA |
CH3(CH2)16COOH |
MOL
WT. |
284.48 |
H.S.
CODE
|
2915.70.0120 |
SMILES |
C(CCCCCCCCCCC)CCCCCC(=O)O
|
TOXICITY
|
|
SYNONYMS |
n-Octadecanoate; 1-Heptadecanecarboxylic acid; |
n-Octadecylic acid; Cetylacetic acid; Acide octadecylique;
Acide stearique; Stearophanic acid; Octadecanoic acid;
Other CAS RN: 8013-28-3, 8023-06-1, 8037-83-0, 8037-40-9,
8039-54-1, 8039-53-0, 8039-52-9, 8039-51-8, 39390-61-9,
58392-66-8, 82497-27-6, 134503-33-6, 197923-10-7, 294203-07-9 |
EXTRA
NOTES
|
EPA Pesticide Chemical Code 079082,
FEMA No. 3035 |
CLASSIFICATION
|
Fatty
Acid |
PHYSICAL AND CHEMICAL PROPERTIES
|
PHYSICAL
STATE |
White to yellowish solid |
MELTING POINT |
67
- 69 C |
BOILING
POINT |
361 |
SPECIFIC GRAVITY |
0.94 |
SOLUBILITY
IN WATER |
0.1-1 g/100 ml at 23 C |
OH RATE |
2.25E-11
(cm3/molecule-sec
at 25 C Atmospheric ) |
VAPOR DENSITY |
9.8 |
HENRY LAW
CONSTANT |
4.76E-07 (atm-m3/mole at 25 C)
Constant |
NFPA
RATINGS
|
Health: 1 Flammability: 1 Reactivity: 0 |
REFRACTIVE
INDEX
|
|
FLASH
POINT |
196
C
|
STABILITY |
Stable
under ordinary conditions |
EXTERNAL LINKS
&GENERAL
DESCRIPTION
|
Wikipedia
Linking
Material
Safety Data Sheet
Google
Scholar Search
GENERAL
DESCRIPTION: Fatty Acids are aliphatic carboxylic acid with varying hydrocarbon lengths
at one end of the chain joined to terminal carboxyl (-COOH) group at the other
end. The general formula is R-(CH2)n-COOH. Fatty acids are
predominantly unbranched and those with even numbers of carbon atoms between 12
and 22 carbons long react with glycerol to form lipids (fat-soluble components
of living cells) in plants, animals, and microorganisms. Fatty acids all have
common names respectively lauric (C12), myrIstic (C14), palmitic (C16),
stearic (C18), oleic (C18, unsaturated), and linoleic (C18, polyunsaturated)
acids. The saturated fatty acids have no double bonds, while oleic acid is an
unsaturated fatty acid has one double bond (also described as olefinic) and
polyunsaturated fatty acids like linolenic acid contain two or more double
bonds. Lauric acid (also called Dodecanoic acid) is the main acid in coconut oil
(45 - 50 percent) and palm kernel oil (45 - 55 percent). Nutmeg butter is rich in
myristic acid (also called Tetradecanoic acid ) which constitutes 60-75 percent
of the fatty-acid content. Palmitic acid(also called Hexadecylic acid )
constitutes between 20 and 30 percent of most animal fats and is also an
important constituent of most vegetable fats (35 - 45 percent of palm oil).
Stearic acid (also called Octadecanoic Acid) is nature's most common
long-chain fatty acids, derived from animal and vegetable fats. It is widely
used as a lubricant and as an additive in industrial preparations. It is used in
the manufacture of metallic stearates, pharmaceuticals, soaps, cosmetics, and
food packaging. It is also used as a softener, accelerator activator and
dispersing agent in rubbers. Oleic acid (systematic chemical name is cis-octadec-9-enoic acid) is the
most abundant of the unsaturated fatty acids in nature. Stearic
Acid is widely used as a lubricant and as an additive in industrial preparations.
It is used in the manufacture of metallic
stearates, pharmaceuticals, soaps, cosmetics, and food packaging.
It is also used as a
softener, accelerator activator and dispersing agent in rubbers.
INDIVIDUAL SATURATED FATTY ACIDS
COMMON NAME |
SYSTEMATIC NAME |
CAS RN |
Length |
MELTING POINT
|
Undecylic Acid
|
n-Hendecanoic Acid |
112-37-8 |
Straight
11:0 |
30 C
|
Lauric
Acid |
n-Dodecanoic Acid |
143-07-7 |
Straight
12:0 |
44
C
|
Tridecylic Acid
|
n-Tridecanoic Acid
|
638-53-9 |
Straight
13:0 |
42 C
|
Myristic Acid |
n-Tetradecanoic Acid |
544-63-8 |
Straight
14:0 |
54
C
|
Pentadecanoic Acid |
n-Pentadecanoic Acid |
1002-84-2 |
Straight 15:0 |
52
C
|
Palmitic
Acid |
n-Hexadecanoic Acid |
57-10-3 |
Straight
16:0 |
62
C
|
Margaric Acid
|
n-Heptadecanoic Acid
|
506-12-7 |
Straight
17:0 |
61 C
|
Stearic
Acid |
n-Octadecanoic
Acid |
57-11-4 |
Straight
18:0 |
70
C
|
Nondecylic Acid
|
n-Nonadecanoic Acid
|
646-30-0 |
Straight
19:0 |
70 C
|
Arachidic Acid |
n-Eicosanoic Acid |
506-30-9 |
Straight 20:0 |
75
C
|
Henicosanoic acid |
n-Heneicosanoic Acid
|
2363-71-5 |
Straight 21:0 |
74 C
|
Behenic Acid |
n-Docosanoic Acid
|
112-85-6 |
Straight 22:0 |
81
C
|
Tricosanoic acid |
n-Tricosanoic acid |
2433-96-7 |
Straight 23:0 |
80 C
|
Lignoceric Acid |
n-Tetracosanoic Acid |
557-59-5 |
Straight 24:0 |
85
C
|
Pentacosanoic Acid
|
n-Pentacosanoic Acid
|
506-38-7 |
Straight 25:0 |
85 C
|
Cerotinic acid |
n-Hexacosanoic acid |
506-46-7 |
Straight 26:0 |
87 C
|
Heptacosanoic Acid
|
n-Heptacosanoic Acid
|
7138-40-1 |
Straight 27:0 |
87 C
|
Montanic acid |
n-Octacosanoic acid |
506-48-9 |
Straight 28:0 |
91 C
|
Nonacosanoic Acid
|
n-Nonacosanoic Acid
|
4250-38-8 |
Straight 29:0 |
91 C
|
Melissic acid |
n-Triacontanoic acid |
506-50-3 |
Straight 30:0 |
93 C
|
|
n-Hentriacontanoic Acid
|
38232-01-8 |
Straight 31:0 |
|
Lacceroic Acid
|
n-Dotriacontanoic Acid |
|
Straight 32:0 |
|
Ceromelissic Acid |
n-Tritriacontanoic acid |
|
Straight 33:0 |
|
Geddic Acid |
n-Tetratriacontanoic acid |
|
Straight 34:0 |
|
Ceroplastic Acid |
n-Pentatriacontanoic acid |
|
Straight 35:0 |
|
|
SALES
SPECIFICATION |
PALM
OIL ACID (HARDENED)
|
APPEARANCE
|
Bead
|
IODINE VALUE |
0.5
max
|
ACID VALUE |
208 -
210 |
SAP VALUE |
209 -
211 |
TITER |
54 - 56
C |
COLOR |
0.5 R / 2.5
Y |
CARBON
DISTRIBUTION |
C14
(1% max) + C16 (62% max) + C18 (45% max)
|
TRANSPORTATION |
PACKING |
25kgs
in bag , 17mts in Container |
HAZARD CLASS |
Not regulated |
UN
NO. |
|
GENERAL
DESCRIPTION OF FAT
|
Commercial fats
produced by organic processes in plants are palm, coconut, palm kernel,
sunflower, soybean, and other oils. Their main components are triolein and
triglyceryl esters of stearic (C18), palmitic (C16), myristic(C14), lauric
(C12), oleic (C18:1), and other fatty acids. Tallow is a refined hard fat
extracted from fatty deposits of animals, especially from suet (fatty tissues
around the kidneys of cattle and sheep). The molecules of most natural fatty
acids have an even number of carbon chains due to the linkage together by ester
units. Analogous compounds of odd numbers carbon chain fatty acids can be made
synthetically. All fats are insoluble in water and have lighter weight than
water. Industrial fats can be sub-classified as fat, grease or oil depending on
melting point. Fats that are liquid at room temperature are referred to oil.
Grease has a higher initial viscosity than oil. It is used as a lubricant. The
organic processes to convert fats to fatty acids (or esters) and glycerol is
called oleochemistry. Fatty acids and glycerol are produced by hydrolysis
(addition reaction of water molecule with cleavage of parent molecules) of the
triglycerides. Fatty esters are produced by esterification reaction. Coconut or
palm oils are better source to get saturated fatty acids than sunflower, soybean
or rapeseed oils which have more unsaturated fatty acids composition of
triglycerides. Tall oil fatty acid (TOFA) is a low cost unsaturated fatty
acid (oleic acid) and is a source of low boiling point fatty acids.
It is an alternative to tallow fatty acid in soap applications. Generally,
commercial coconut fatty acid has carbon chain composition of; C10 (5% max) +
C12 (45 - 55%) + C14 (20 - 25%) + C16 (10 - 15 %) + C18 (10 - 15% max, including
unsaturated fatty acids). Fats are used to make soap, food products, cosmetics,
and candles, and lubricants. They are wisely used in producing synthetic
surfactants.
|
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